Work done by a gas

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In the expression for work done by a gas integral(Pdv) aren't we supposed to use internal pressure?
Moreover work done by gas is the work done by the force exerted by th gas,but everywhere i find people using external pressure instead of internal pressure










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  • In equilibrium, the pressure exerted by a gas on the walls ("internal pressure") is equal to the pressure exerted by the walls on the gas ("external pressure"). Thermodynamics deals with transitions between a series of equilibrium states.
    – probably_someone
    30 mins ago










  • @probably_someone The issue might be that if the pressure is changing, then it can't always be equal to the external pressure.
    – Aaron Stevens
    28 mins ago










  • @probably_someone external pressure is equal to internal pressure if the piston is massless..but that is not true if the piston has sufficient mass
    – Alfred Mathew
    25 mins ago










  • @probably_someone moreover in a thermodynamic process equilibrium need not be there in the intermediate stages
    – Alfred Mathew
    23 mins ago














up vote
4
down vote

favorite












In the expression for work done by a gas integral(Pdv) aren't we supposed to use internal pressure?
Moreover work done by gas is the work done by the force exerted by th gas,but everywhere i find people using external pressure instead of internal pressure










share|cite







New contributor




Alfred Mathew is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.



















  • In equilibrium, the pressure exerted by a gas on the walls ("internal pressure") is equal to the pressure exerted by the walls on the gas ("external pressure"). Thermodynamics deals with transitions between a series of equilibrium states.
    – probably_someone
    30 mins ago










  • @probably_someone The issue might be that if the pressure is changing, then it can't always be equal to the external pressure.
    – Aaron Stevens
    28 mins ago










  • @probably_someone external pressure is equal to internal pressure if the piston is massless..but that is not true if the piston has sufficient mass
    – Alfred Mathew
    25 mins ago










  • @probably_someone moreover in a thermodynamic process equilibrium need not be there in the intermediate stages
    – Alfred Mathew
    23 mins ago












up vote
4
down vote

favorite









up vote
4
down vote

favorite











In the expression for work done by a gas integral(Pdv) aren't we supposed to use internal pressure?
Moreover work done by gas is the work done by the force exerted by th gas,but everywhere i find people using external pressure instead of internal pressure










share|cite







New contributor




Alfred Mathew is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.











In the expression for work done by a gas integral(Pdv) aren't we supposed to use internal pressure?
Moreover work done by gas is the work done by the force exerted by th gas,but everywhere i find people using external pressure instead of internal pressure







thermodynamics






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Alfred Mathew is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.











share|cite







New contributor




Alfred Mathew is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.









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Alfred Mathew is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.









asked 36 mins ago









Alfred Mathew

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New contributor




Alfred Mathew is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.





New contributor





Alfred Mathew is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.






Alfred Mathew is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.











  • In equilibrium, the pressure exerted by a gas on the walls ("internal pressure") is equal to the pressure exerted by the walls on the gas ("external pressure"). Thermodynamics deals with transitions between a series of equilibrium states.
    – probably_someone
    30 mins ago










  • @probably_someone The issue might be that if the pressure is changing, then it can't always be equal to the external pressure.
    – Aaron Stevens
    28 mins ago










  • @probably_someone external pressure is equal to internal pressure if the piston is massless..but that is not true if the piston has sufficient mass
    – Alfred Mathew
    25 mins ago










  • @probably_someone moreover in a thermodynamic process equilibrium need not be there in the intermediate stages
    – Alfred Mathew
    23 mins ago
















  • In equilibrium, the pressure exerted by a gas on the walls ("internal pressure") is equal to the pressure exerted by the walls on the gas ("external pressure"). Thermodynamics deals with transitions between a series of equilibrium states.
    – probably_someone
    30 mins ago










  • @probably_someone The issue might be that if the pressure is changing, then it can't always be equal to the external pressure.
    – Aaron Stevens
    28 mins ago










  • @probably_someone external pressure is equal to internal pressure if the piston is massless..but that is not true if the piston has sufficient mass
    – Alfred Mathew
    25 mins ago










  • @probably_someone moreover in a thermodynamic process equilibrium need not be there in the intermediate stages
    – Alfred Mathew
    23 mins ago















In equilibrium, the pressure exerted by a gas on the walls ("internal pressure") is equal to the pressure exerted by the walls on the gas ("external pressure"). Thermodynamics deals with transitions between a series of equilibrium states.
– probably_someone
30 mins ago




In equilibrium, the pressure exerted by a gas on the walls ("internal pressure") is equal to the pressure exerted by the walls on the gas ("external pressure"). Thermodynamics deals with transitions between a series of equilibrium states.
– probably_someone
30 mins ago












@probably_someone The issue might be that if the pressure is changing, then it can't always be equal to the external pressure.
– Aaron Stevens
28 mins ago




@probably_someone The issue might be that if the pressure is changing, then it can't always be equal to the external pressure.
– Aaron Stevens
28 mins ago












@probably_someone external pressure is equal to internal pressure if the piston is massless..but that is not true if the piston has sufficient mass
– Alfred Mathew
25 mins ago




@probably_someone external pressure is equal to internal pressure if the piston is massless..but that is not true if the piston has sufficient mass
– Alfred Mathew
25 mins ago












@probably_someone moreover in a thermodynamic process equilibrium need not be there in the intermediate stages
– Alfred Mathew
23 mins ago




@probably_someone moreover in a thermodynamic process equilibrium need not be there in the intermediate stages
– Alfred Mathew
23 mins ago










1 Answer
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5
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The work done by an expanding gas is the energy transferred to its surroundings. In effect, as the gas expands it is compressing its surroundings so the work done is the force exerted on the surroundings (i.e. the pressure of the surroundings times the area) times the distance moved.



The extreme case of this is a Joule expansion where a gas expands into a vacuum i.e. the pressure of the surroundings is zero. In this case the expanding gas does no work regardless of the initial pressure of the gas.






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  • force exerted on the surroundings is pressure exerted by the gas times the area,not external pressure
    – Alfred Mathew
    21 mins ago






  • 1




    @AlfredMathew imagine you're compressing a spring with your hand. No matter how hard (how much force) you push with your hand, it's the $kx^2$ force from the spring that determines the work/energy that gets stored in it.
    – John Forkosh
    17 mins ago










  • @John Forkosh That is because the spring is massless..and by newtons second law there must be no net force,hence the force we apply is equal to the force exerted by the spring
    – Alfred Mathew
    5 mins ago










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1 Answer
1






active

oldest

votes








1 Answer
1






active

oldest

votes









active

oldest

votes






active

oldest

votes








up vote
5
down vote













The work done by an expanding gas is the energy transferred to its surroundings. In effect, as the gas expands it is compressing its surroundings so the work done is the force exerted on the surroundings (i.e. the pressure of the surroundings times the area) times the distance moved.



The extreme case of this is a Joule expansion where a gas expands into a vacuum i.e. the pressure of the surroundings is zero. In this case the expanding gas does no work regardless of the initial pressure of the gas.






share|cite|improve this answer




















  • force exerted on the surroundings is pressure exerted by the gas times the area,not external pressure
    – Alfred Mathew
    21 mins ago






  • 1




    @AlfredMathew imagine you're compressing a spring with your hand. No matter how hard (how much force) you push with your hand, it's the $kx^2$ force from the spring that determines the work/energy that gets stored in it.
    – John Forkosh
    17 mins ago










  • @John Forkosh That is because the spring is massless..and by newtons second law there must be no net force,hence the force we apply is equal to the force exerted by the spring
    – Alfred Mathew
    5 mins ago














up vote
5
down vote













The work done by an expanding gas is the energy transferred to its surroundings. In effect, as the gas expands it is compressing its surroundings so the work done is the force exerted on the surroundings (i.e. the pressure of the surroundings times the area) times the distance moved.



The extreme case of this is a Joule expansion where a gas expands into a vacuum i.e. the pressure of the surroundings is zero. In this case the expanding gas does no work regardless of the initial pressure of the gas.






share|cite|improve this answer




















  • force exerted on the surroundings is pressure exerted by the gas times the area,not external pressure
    – Alfred Mathew
    21 mins ago






  • 1




    @AlfredMathew imagine you're compressing a spring with your hand. No matter how hard (how much force) you push with your hand, it's the $kx^2$ force from the spring that determines the work/energy that gets stored in it.
    – John Forkosh
    17 mins ago










  • @John Forkosh That is because the spring is massless..and by newtons second law there must be no net force,hence the force we apply is equal to the force exerted by the spring
    – Alfred Mathew
    5 mins ago












up vote
5
down vote










up vote
5
down vote









The work done by an expanding gas is the energy transferred to its surroundings. In effect, as the gas expands it is compressing its surroundings so the work done is the force exerted on the surroundings (i.e. the pressure of the surroundings times the area) times the distance moved.



The extreme case of this is a Joule expansion where a gas expands into a vacuum i.e. the pressure of the surroundings is zero. In this case the expanding gas does no work regardless of the initial pressure of the gas.






share|cite|improve this answer












The work done by an expanding gas is the energy transferred to its surroundings. In effect, as the gas expands it is compressing its surroundings so the work done is the force exerted on the surroundings (i.e. the pressure of the surroundings times the area) times the distance moved.



The extreme case of this is a Joule expansion where a gas expands into a vacuum i.e. the pressure of the surroundings is zero. In this case the expanding gas does no work regardless of the initial pressure of the gas.







share|cite|improve this answer












share|cite|improve this answer



share|cite|improve this answer










answered 26 mins ago









John Rennie

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265k41518766











  • force exerted on the surroundings is pressure exerted by the gas times the area,not external pressure
    – Alfred Mathew
    21 mins ago






  • 1




    @AlfredMathew imagine you're compressing a spring with your hand. No matter how hard (how much force) you push with your hand, it's the $kx^2$ force from the spring that determines the work/energy that gets stored in it.
    – John Forkosh
    17 mins ago










  • @John Forkosh That is because the spring is massless..and by newtons second law there must be no net force,hence the force we apply is equal to the force exerted by the spring
    – Alfred Mathew
    5 mins ago
















  • force exerted on the surroundings is pressure exerted by the gas times the area,not external pressure
    – Alfred Mathew
    21 mins ago






  • 1




    @AlfredMathew imagine you're compressing a spring with your hand. No matter how hard (how much force) you push with your hand, it's the $kx^2$ force from the spring that determines the work/energy that gets stored in it.
    – John Forkosh
    17 mins ago










  • @John Forkosh That is because the spring is massless..and by newtons second law there must be no net force,hence the force we apply is equal to the force exerted by the spring
    – Alfred Mathew
    5 mins ago















force exerted on the surroundings is pressure exerted by the gas times the area,not external pressure
– Alfred Mathew
21 mins ago




force exerted on the surroundings is pressure exerted by the gas times the area,not external pressure
– Alfred Mathew
21 mins ago




1




1




@AlfredMathew imagine you're compressing a spring with your hand. No matter how hard (how much force) you push with your hand, it's the $kx^2$ force from the spring that determines the work/energy that gets stored in it.
– John Forkosh
17 mins ago




@AlfredMathew imagine you're compressing a spring with your hand. No matter how hard (how much force) you push with your hand, it's the $kx^2$ force from the spring that determines the work/energy that gets stored in it.
– John Forkosh
17 mins ago












@John Forkosh That is because the spring is massless..and by newtons second law there must be no net force,hence the force we apply is equal to the force exerted by the spring
– Alfred Mathew
5 mins ago




@John Forkosh That is because the spring is massless..and by newtons second law there must be no net force,hence the force we apply is equal to the force exerted by the spring
– Alfred Mathew
5 mins ago










Alfred Mathew is a new contributor. Be nice, and check out our Code of Conduct.









 

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